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3.4K views · 106 reactions | The synthesis and isolation of a heavier nitrile featuring phosphino-silylene stabilized by an N-heterocyclic carbene is reported in Nature Chemistry ( https://ccdc-info.com/4divDxf). CSD Entry HOXREV shows a bent R–Si–P geometry that fundamentally differs from the classical nitriles.  https://ccdc-info.com/3BaWsGy #FeaturedStructureFriday #Crystallography | Cambridge Crystallographic Data Centre (CCDC) | Facebook
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